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Furthermore, individual countries continue to look at introducing their own legislative initiatives in regard to these flame retardants, and thus is always important to check the status of these efforts 7422 Flame-Retardant Chemistry Polymer combustion occurs in a continuous cycle, as highlighted in Fig 714 Heat generated in the flame is transferred back to the polymer surface, producing volatile polymer fragments that constitute fuel for further burning These fragments diffuse into the flame zone, where they react with oxygen by free-radical chain reactions This in turn produces more heat and continues the cycle Flame retardancy is achieved by interrupting this cycle There are two basic ways to interrupt this cycle One method is called solid phase inhibition and involves changes in the polymer substrate Systems that promote extensive polymer crosslinking at the surface form a carbonaceous char upon heating.

The char then insulates the underlying polymer from the heat of the flame, preventing production of new fuel and further burning Other systems evolve water during heating, cooling the surface and increasing the amount of energy needed to maintain the flame The second method is called vapor phase inhibition and involves changes in the flame chemistry Reactive species are built into the polymer that are transformed into volatile freeradical inhibitors during burning These materials diffuse into the flame and inhibit the branching radical reactions As a result, increased energy is required to maintain the flame and the cycle is interrupted For many materials, both solid and vapor phase inhibition occur Polymers, including the various types of epoxy resins, differ in their inherent flammability.

c Practice in front of a mirror, in front of your dog, and in front of friends As your comfort with what you are going to say rises, so will your con dence d Relax Practice deep abdominal breathing before you practice your presentation, as part of your practice, and immediately before the presentation e Relax Practice isometric muscle tensing, starting at your head and ending with your toes Contract and squeeze the muscles, and then release f Take the day before the presentation off That s correct: no practice the day prior to the presentation Sleep well, and eat a light meal several hours before the presentation 3 Make it memorable a Think about a presenter who captured your attention.

The types of resins and curing agents selected can impact the fundamental flammability of the resin system and determine how much additional flame-retardant components are needed to achieve the desired flammability rating For example, polymers with a high concentration of.

TABLE 52.6 PTHs with Component Leads: Minimum Acceptable Solder Conditionsa Criteria A. Vertical fill of solderb,c Note: Less than 100 percent older fill may not be acceptable in some applications: e.g., thermal shock. The user is responsible for identifying these situations to the manufacturer B. Wetting on primary side (solder destination side) of lead and barrel Target for Classes 1,2, and 3 is 360 wetting present on land and barrel C. Percentage of land area covered with wetted solder on primary side (solder destination side) The land area does not need to be wetted with solder on the primary side D. Fillet and wetting on secondary side (solder source side) of lead and barrel E. Percentage of land area covered with wetted solder on secondary side (solder source side) Class 1 Not Specified Class 2 75% Class 3 75%

Now we consider the radial coordinate. We have F = r d ds 2 r 2m 1 r = 2 4m r 2 ( )2 r 2m r 1 r

180

270

270 75%

270 75%

330 75%

Notes: a Wetted solder refers to solder applied by the solder process. b The 25 percent unfilled height includes both source and destination side depressions. c Class 2 may have less than 75 percent vertical hole fill.

FIGURE 52.23 (1) Vertical fill meets requirements of Table 52.6 (2) Solder distination side (3) Solder source side. (IPC)

52.6.2 Solder Balls or Solder Splash Solder balls and splashes that violate minimum electrical design clearance, are not encapsulated in a permanent coating, or are not attached (soldered) to a metal surface are unacceptable (see Fig. 52.24). 52.6.3 Dewetting and Nonwetting Dewetting is a condition that results when molten solder coats a surface and then recedes to leave irregularly shaped mounds of solder that are separated by areas that are covered with a

What was it about this person that engaged you Think of what you are passionate about, and utilize it in your presentation content, in your delivery style, or in your personal stories and facts b Remember, people may not remember what you say, but they will remember how you make them feel Decide how you want your audience to feel about your message and how you will need to act to make the audience understand your message..

thin film of solder and with the basis metal not exposed (see Fig. 52.25). Nonwetting is the partial adherence of molten solder to a surface that it has contacted, while the basis metal remains exposed (see Fig. 52.26).

FIGURE 52.25 Example of dewetting. (IPC)

FIGURE 52.26 Example of non wetting. (IPC)